Hydrodeoxygenation of methyl-substituted ketones using the composite loading of hydrogenation and dehydration catalysts

• Published in: Catalysis in industry Vol. 9; no. 4; pp. 299 - 307
• Main Authors: Ivanov, D. P., Kharitonov, A. S., Pirutko, L. V., Noskov, A. S., Abrashenkov, P. A., Golovachev, V. A., Kondrashev, D. O., Kleimenov, A. V.
• Format: Journal Article
• Language: English
• Published: Moscow Pleiades Publishing 01.10.2017; Springer Nature B.V
• Subjects: Carbonyl compounds; Carbonyls; Catalysis; Catalysis in Chemical and Petrochemical Industry; Catalysts; Chemistry; Chemistry and Materials Science; Control stability; Dehydration; Hydrogenation; Ketones; Motor fuels; Pentanone; Substitutes; dehydration catalysts; methyl-substituted carbonyl compounds; hydrodeoxygenation; hydrogenation catalysts; 2,4-dimethyl-3-pentanone; composite catalysts loading; high-octane components
• ISSN: 2070-0504; 2070-0555
• DOI: 10.1134/S2070050417040043

The hydrogenation/hydrodeoxygenation of methyl-substituted carbonyl compounds to preserve the isomeric structure of a product is one way of controlling its amount of oxygen and improving the chemical stability of motor fuel components. The integration of hydrogenation and dehydration catalysts in one reaction space is an bright example of processes that proceed on these catalysts and positively affect each other. In comparison with the hydrogenation Ni-catalyst, the transformation of 2,4-dimethyl-3-pentanone into 2,4-dimethylpentane over the same catalyst loaded jointly with a zeolite is accompanied by a several-fold increase in hydrogenation rate and operational stability. In the process, the complete hydrodeoxygenation of the parent ketone is observed. Such composite loading can be used to replace bifunctional catalysts.