Diene Synthesis and One-Pot Processes in the Presence of Solutions of Mo–V–P Heteropoly Acids

This review—which is based on the authors’ original studies—is devoted to application of aqueous solutions of Mo–V–P heteropoly acids (HPA- x , where x is the number of vanadium atoms) as bifunctional (acidic and oxidative) catalysts. The focus is on the development of one-pot processes in which the...

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Bibliographic Details
Published inKinetics and catalysis Vol. 61; no. 4; pp. 516 - 529
Main Authors Gogin, L. G., Zhizhina, E. G.
Format Journal Article
LanguageEnglish
Published Moscow Pleiades Publishing 01.07.2020
Springer Nature B.V
Subjects
Acidic oxides
Adducts
Anthraquinones
Aqueous solutions
Atomic properties
Catalysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Oxidation
Physical Chemistry
Vanadium
oxidation
naphthoquinone
anthraquinone
diene synthesis
heteropoly acids
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Summary:This review—which is based on the authors’ original studies—is devoted to application of aqueous solutions of Mo–V–P heteropoly acids (HPA- x , where x is the number of vanadium atoms) as bifunctional (acidic and oxidative) catalysts. The focus is on the development of one-pot processes in which the acid-catalyzed reaction of diene synthesis is combined with the oxidation of the produced adducts. Prospects for the design of a number of industrial processes for the production of substituted 1,4-naphtho- and 9,10-anthraquinones in the presence of solutions of modified non-Keggin HPA- x are shown.
ISSN:0023-1584
1608-3210
DOI:10.1134/S0023158420030118