Optimized structure stability and electrochemical performance of LiNi0.8Co0.15Al0.05O2 by sputtering nanoscale ZnO film

• Published in: Journal of power sources Vol. 309; pp. 20 - 26
• Main Authors: Lai, Yan-Qing, Xu, Ming, Zhang, Zhi-An, Gao, Chun-Hui, Wang, Peng, Yu, Zi-Yang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 31.03.2016
• Subjects: Cathode materials; LiNi0.8Co0.15Al0.05O2; Lithium-ion batteries; Magnetron sputtering; ZnO surface modification; Lithium-ion batteries; LiNi0.8Co0.15Al0.05O2; Magnetron sputtering; ZnO surface modification; Cathode materials
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2016.01.079

LiNi0.8Co0.15Al0.05O2 (NCA) is one of the most promising cathode material for lithium-ion batteries (LIBs) in electric vehicles, which is successfully adopted in Tesla. However, the dissolution of the cation into the electrolyte is still a one of the major challenges (fading capacity and poor cyclability, etc.) presented in pristine NCA. Herein, a homogeneous nanoscale ZnO film is directly sputtered on the surface of NCA electrode via the magnetron sputtering (MS). This ZnO film is evidenced by scanning electron microscopy (SEM), transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The results clearly demonstrate that ZnO film is fully and uniformly covered on the NCA electrodes. After 90 cycles at 1.0C, the optimized MS-2min coated NCA electrode delivers much higher discharge capacity with 169 mAh g−1 than that of the pristine NCA electrode with 127 mAh g−1. In addition, the discharge capacity also reaches 166 mAh g−1 at 3.0C, as compared to that of 125 mAh g−1 for the pristine electrode. The improved electrochemical performance can be ascribed to the superiority of the MS ZnO film that reduce charge transfer resistance and protect the NCA electrode from cation dissolution. [Display omitted] •ZnO coated LiNi0.8Co0.15Al0.05O2 (NCA) is prepared by magnetron sputtering (MS).•ZnO film is fully and conformally coated on the surface of NCA particles.•The cyclic performance and rate capability of NCA are greatly improved.•The optimized MS ZnO coated NCA is promising and economical for application.