Concise synthesis of the tricyclic skeleton of crotobarin and crotogoudin via a gold-catalyzed cycloisomerization reaction

A concise synthesis of the tricyclic skeleton of crotobarin and crotogoudin via a gold-catalyzed 1,6-enyne cycloisomerization reaction is reported.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 51; no. 5; pp. 889 - 891
Main Authors Guo, Yinliang, Liu, Qiang, Jia, Yanxing
Format Journal Article
LanguageEnglish
Published England 18.01.2015
Subjects
Catalysis
Chemistry Techniques, Synthetic
Cyclization
Diterpenes - chemical synthesis
Diterpenes - chemistry
Gold - chemistry
Isomerism
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Summary:A concise synthesis of the tricyclic skeleton of crotobarin and crotogoudin via a gold-catalyzed 1,6-enyne cycloisomerization reaction is reported.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc48897g