Starch-assisted electrochemical fabrication of high surface area cobalt hydroxide nanosheets for high performance supercapacitors

• Published in: Journal of materials science. Materials in electronics Vol. 28; no. 15; pp. 11406 - 11414
• Main Authors: Aghazadeh, Mustafa, Ganjali, Mohammad Reza
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.08.2017; Springer Nature B.V
• Subjects: Capacitance; Characterization and Evaluation of Materials; Chemical plants; Chemistry and Materials Science; Cobalt; Construction contracts; Current density; Cycles; Direct current; Discharge; Electrochemical fabrication; Electrodeposition; Loads (forces); Materials Science; Mesoscale phenomena; Nanosheets; Optical and Electronic Materials; Phase (cyclic); Porosity; Sheets; Supercapacitors; Surface area; Voltammetry; Equivalent Series Resistance; Cobalt Hydroxide; Working Electrode; Cyclic Voltammetry Profile; Cyclic Voltammetry
• ISSN: 0957-4522; 1573-482X
• DOI: 10.1007/s10854-017-6935-1

High surface area β-Co(OH) 2 nanosheets is electro-synthesized through a simple deposition procedure, and their performance as supercapacitor electrode material is investigated. Cathodic electrodeposition of cobalt hydroxide was performed from 0.005 M CoCl 2 at the direct current (DC) mode with applying current density of 10 mA cm −2 and RT conditions. The obtained green deposit was characterized through XRD, IR, SEM, BET and TEM analyses. The result indicated that the electrodeposited sample has pure beta cobalt hydroxide phase with uniform hexagonal sheets. BET analysis showed that the prepared hydroxide has high surface area of 157.2 m 2  g −1 with mesoscale pores. The charge storage ability of the prepared β-Co(OH) 2 nanosheets were measured by cyclic voltammetry and continuous charge–discharge techniques, which revealed that the produced nanosheets are capable to deliver specific capacitance as high as 886.8 and 734.3 Fg −1 at the current loads of 1 and 3 A g −1 , respectively, and capacity retentions of 93.9 and 83.7% after 3000 continuous cycling at these current loads. These electrochemical data proved the suitability of the prepared material for use in supercapacitor.