Complexes of Nitrilotriacetic Acid with Amines. Molecular Structures of 2-Ammonioethanol Nitrilotriacetate and Bis{2-Ammonio-2-(Hydroxymethyl)propane-1,3-Diol} Nitrilotriacetate
Reactions of nitrilotriacetic acid with 2-aminoethanol, 2-amino-2-(hydroxymethyl)propane-1,3-diol, and 2,2'-(ethylenedioxy)bis(ethylamine) afford the following salts in high yields: 2-ammonioethanol nitrilotriacetate [HN + (CH 2 COO – ) 2 (CH 2 COOH) ⋅ H 3 N + CH 2 CH 2 OH] n , bis{2-ammonio-2-...
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Published in | Crystallography reports Vol. 66; no. 3; pp. 441 - 447 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
Moscow
Pleiades Publishing
01.05.2021
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
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Summary: | Reactions of nitrilotriacetic acid with 2-aminoethanol, 2-amino-2-(hydroxymethyl)propane-1,3-diol, and 2,2'-(ethylenedioxy)bis(ethylamine) afford the following salts in high yields: 2-ammonioethanol nitrilotriacetate [HN
+
(CH
2
COO
–
)
2
(CH
2
COOH) ⋅ H
3
N
+
CH
2
CH
2
OH]
n
, bis{2-ammonio-2-(hydroxymethyl)propane-1,3-diol} nitrilotriacetate HN
+
(CH
2
COO
–
)
3
⋅ 2H
3
N
+
C(CH
2
OH)
3
, and 2,2'-(ethylenedioxy)bis(ethylammonium) nitrilotriacetate HN
+
(CH
2
COO
–
)
3
⋅ H
3
N
+
CH
2
CH
2
OCH
2
CH
2
OCH
2
CH
2
N
+
H
3
. The molecular structures of 2-ammonioethanol nitrilotriacetate and bis{2-ammonio-2-(hydroxymethyl)propane-1,3-diol} nitrilotriacetate were determined. Nitrilotriacetic acid molecules in 2-ammonioethanol nitrilotriacetate are linked by O⋅⋅⋅H⋅⋅⋅O hydrogen bonds involving acid groups of adjacent molecules to form a polymer chain. On the contrary, nitrilotriacetic acid molecules in bis{2-ammonio-2-(hydroxymethyl)propane-1,3-diol} nitrilotriacetate do not form polymer chains. In the crystals of both compounds, adjacent molecules are linked by numerous O⋅⋅⋅H interactions to form infinite 3D frameworks. |
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ISSN: | 1063-7745 1562-689X |
DOI: | 10.1134/S1063774521030214 |