Spectral, coordination and thermal properties of 5-arylidene thiobarbituric acids
[Display omitted] ► 5-Arylidine thiobarbituric acids and their complexes were synthesized. ► The stereochemistry and mode of bonding were investigated. ► The ligands were of bidentate and tridentate nature. ► The complexes were of octahedral configuration with certain thermal stability. Synthesis of...
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Published in | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 107; pp. 179 - 187 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
England
Elsevier B.V
15.04.2013
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Subjects | |
Online Access | Get full text |
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Summary: | [Display omitted]
► 5-Arylidine thiobarbituric acids and their complexes were synthesized. ► The stereochemistry and mode of bonding were investigated. ► The ligands were of bidentate and tridentate nature. ► The complexes were of octahedral configuration with certain thermal stability.
Synthesis of 5-arylidine thiobarbituric acids containing different functional groups with variable electronic characters were described and their Co2+, Ni2+ and Cu2+ complexes. The stereochemistry and mode of bonding of 5-(substituted benzylidine)-2-TBA complexes were achieved based on elemental analysis, spectral (UV–VIS, IR, 1H NMR, MS), magnetic susceptibility and conductivity measurements. The ligands were of bidentate and tridentate bonding through S, N and O of pyrimidine nucleolus. All complexes were of octahedral configuration. The thermal data of the complexes pointed to their stability. The mechanism of the thermal decomposition is discussed. The thermodynamic parameters of the dissociation steps were evaluated and discussed. |
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ISSN: | 1386-1425 1873-3557 |
DOI: | 10.1016/j.saa.2013.01.022 |