Synchronous double C-N bond formation via C-H activation for a novel synthetic route to phenazine

A novel synthetic strategy for phenazine formation is reported following self-coupling of anilines by Pd-Ag binary nanocluster-catalysed synchronous double C-N bond formation via non-radical mode of ortho-aryl C-H activation.

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 52; no. 5; pp. 922 - 925
Main Authors Seth, Kapileswar, Roy, Sudipta Raha, Chakraborti, Asit K.
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2016
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SELECTIVE DEPROTECTION
CROSS-COUPLING REACTIONS
CHEMOSELECTIVE METHOD
VIRTUALLY NEUTRAL CONDITIONS
ARYL ALKYL ETHERS
IN-SITU GENERATION
PALLADIUM NANOPARTICLES
THIOPHENOLATE ANION
CATALYZED DIRECT ARYLATION
EFFICIENT PROTOCOL
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Summary:A novel synthetic strategy for phenazine formation is reported following self-coupling of anilines by Pd-Ag binary nanocluster-catalysed synchronous double C-N bond formation via non-radical mode of ortho-aryl C-H activation.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc08640j