Heptane Reforming over Pt–Re/Al2O3: Reaction Network, Kinetics, and Apparent Selective Catalyst Deactivation

• Published in: Journal of catalysis Vol. 206; no. 2; pp. 188 - 201
• Main Authors: Liu, K., Fung, S.C., Ho, T.C., Rumschitzki, D.S.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier Inc 10.03.2002; Elsevier
• Subjects: Catalysis; Catalytic reactions; Chemistry; Exact sciences and technology; General and physical chemistry; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Mixed catalyst; Deactivation; Catalyst selectivity; Reaction path; Transition metal; Reforming; Heptane; Supported catalyst; Heterogeneous catalysis; Kinetic model; Platinum; Kinetics; Rhenium; Alumina
• ISSN: 0021-9517; 1090-2694
• DOI: 10.1006/jcat.2001.3485

This is a continuation of our previous work aimed at developing a fundamental, a priori model for predicting how a reforming catalyst deactivates in a fixed-bed reactor due to coke formation. Specifically, we construct a lumped reaction network for n-heptane reforming on a bifunctional Pt–Re/Al2O3 catalyst using both differential and integral rate data. The data are obtained from a vibrational microbalance and a multioutlet fixed-bed reactor with n-heptane or reaction intermediates as the feed. The network, including a five-membered naphthene lump that is the primary coke precursor, has a minimum number of reactions and corresponding adjustable rate parameters, almost all of which are individually determined by targeted experiments. The resulting kinetic model, coupled with a previously developed catalyst coking kinetic model, correctly predicts the long-term spatiotemporal behavior of product composition and coke-on-catalyst for a fixed-bed reformer. The results strongly suggest the need to partition the reforming reactions into two subgroups: those that are significantly affected by coke and those that are not. The approach taken here, which provides both fundamental insights and a quantitative basis for improving catalysts and processes, can also be extended to other catalytic systems.