Substitution-Type Thermal 1,2-Rearrangement. Synthesis of Chiral β-Aryl(or Alkenyl) α-Oxo Nitrile Acetal

Title compound was synthesized via a substitution-type thermal 1,2-rearrangement accompanied by introduction of a cyano group, and derived into the corresponding aldehyde, alkanoic acid, and amide.

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Bibliographic Details
Published inBulletin of the Chemical Society of Japan Vol. 60; no. 7; pp. 2698 - 2700
Main Authors Honda, Yutaka, Tsuchihashi, Gen-ichi
Format Journal Article
LanguageEnglish
Published TOKYO The Chemical Society of Japan 01.07.1987
Chemical Soc Japan
Chemical Society of Japan
Subjects
Chemistry
Chemistry, Multidisciplinary
Exact sciences and technology
Noncondensed benzenic compounds
Organic chemistry
Physical Sciences
Preparations and properties
Science & Technology
Chemical rearrangement
Ketoaldehyde
Ketoamide
Aliphatic compound
Ketonitrile
Saturated compound
Thermal reaction
Oxygen heterocycle
Sulfonate
Acetal
Six membered ring
Benzenic compound
Cyaniding
Ketoacid
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Summary:Title compound was synthesized via a substitution-type thermal 1,2-rearrangement accompanied by introduction of a cyano group, and derived into the corresponding aldehyde, alkanoic acid, and amide.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.60.2698