Efficient photocatalytic selective nitro-reduction and C-H bond oxidation over ultrathin sheet mediated CdS flowers

We report here a visible light driven selective nitro-reduction and oxidation of saturated sp3 C-H bonds using ultrathin (0.8 nm) sheet mediated uniform CdS flowers as catalyst under a household 40 W CFL lamp and molecular oxygen as oxidant. The CdS flowers were synthesized using a simple surfactant...

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Published inChemical communications (Cambridge, England) Vol. 51; no. 51; pp. 10322 - 10325
Main Authors Pahari, Sandip Kumar, Pal, Provas, Srivastava, Divesh N., Ghosh, Subhash Ch, Panda, Asit Baran
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.06.2015
Subjects
Cadmium Compounds - chemistry
Carbon - chemistry
Catalysis
Chemistry
Chemistry, Multidisciplinary
Coordination Complexes - chemistry
Hydrazines - chemistry
Hydrogen - chemistry
Nanoparticles - chemistry
Nitrophenols - chemistry
Oxidation-Reduction
Oxygen - chemistry
Photochemical Processes
Physical Sciences
Science & Technology
Sulfides - chemistry
NANOCOMPOSITES
ACTIVATION
EVOLUTION
COCATALYSTS
GRAPHENE
HYDROGEN-PRODUCTION
NANOSHEETS
NANOSTRUCTURES
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Summary:We report here a visible light driven selective nitro-reduction and oxidation of saturated sp3 C-H bonds using ultrathin (0.8 nm) sheet mediated uniform CdS flowers as catalyst under a household 40 W CFL lamp and molecular oxygen as oxidant. The CdS flowers were synthesized using a simple surfactant assisted hydrothermal method.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01685a