The Effect of the Temperature–Time Mode of Crystallization on the Morphology and Thermal Properties of Nanocomposites Based on Polypropylene and Magnetite (Fe3O4)

• Published in: Journal of inorganic and organometallic polymers and materials Vol. 28; no. 3; pp. 1171 - 1177
• Main Authors: Ramazanov, M. A., Maharramov, A. M., Hajiyeva, F. V., Shirinova, H. A., Di Palma, Luca
• Format: Journal Article
• Language: English
• Published: New York Springer US 01.05.2018; Springer Nature B.V
• Subjects: Atomic force microscopes; Atomic force microscopy; Chemistry; Chemistry and Materials Science; Cooling rate; Crystallization; Degree of crystallinity; Fish; Gravimetric analysis; Inorganic Chemistry; Iron oxides; Magnetic properties; Morphology; Nanocomposites; Organic Chemistry; Polymer Sciences; Polypropylene; Stability analysis; Thermal stability; Thermodynamic properties; Thermal properties; Polypropylene; Magnetite
• ISSN: 1574-1443; 1574-1451
• DOI: 10.1007/s10904-017-0767-6

In the present study, the influence of the temperature–time mode of crystallization (TTC) on the morphology and thermal properties of PP/Fe 3 O 4 nanocomposite materials was investigated. The morphology of the nanocomposites prepared in different TTC mode was studied by atomic force microscope. AFM study shows that the root mean square roughness of samples is 90–95, 50, 21 nm for PP/Fe 3 O 4 @20, PP/Fe 3 O 4 @200 and PP/Fe 3 O 4 @20000 respectively. Thermo gravimetric analysis was employed to investigate the thermal stability of PP/Fe 3 O 4 nanocomposites obtained applying different TTC modes. It was found that thermal stability of water-cooled nanocomposite samples (PP/Fe 3 O 4 @200) is higher than the thermal stability of samples obtained with other two modes. Crystallization and melting behaviors of nanocomposite samples prepared in different TTC mode have been studied with DSC method and the degree of crystallinity of samples was calculated. It was found that, degree of crystalization decreases with increasing of cooling rate. The XRD patterns of samples produced in different TTC modes also correlate well with this result.