New polymeric polyol for thermoset coatings: Superacid-catalyzed copolymerization of water and epoxy resins

• Published in: JCT, Journal of Coatings Technology Vol. 74; no. 928; pp. 33 - 47
• Main Authors: WALKER, Frederick H, DICKENSON, John B, HEGEDUS, Charles R, PEPE, Frank R, KELLER, Renee
• Format: Conference Proceeding Journal Article Trade Publication Article
• Language: English
• Published: Blue Bell, PA Federation of Societies for Coatings Technology 01.05.2002
• Subjects: Acids; Applied sciences; Catalysis; Chemical industry; Chemical reactions; Coatings. Paints, varnishes and inks; Components, formulation; Copolymerization; Emulsion polymerization; Epoxy resins; Equilibrium; Exact sciences and technology; Free radicals; Molecular weight; Organic polymers; Phosphate esters; Physicochemistry of polymers; Polymer industry, paints, wood; Preparation, kinetics, thermodynamics, mechanism and catalysts; Protective coatings; Reagents; Spectrum analysis; Water; Coating material; Emulsion copolymerization; Ether; Epoxy resin; Mechanical properties; Paint film; Acid catalysis; Paint; Experimental study; Binders; Physical properties; Solution polymerization; Thermosetting resin; Bisphenol A; Emulsion polymerization; Formulation; Superacid; Polyol; Chemical properties
• ISSN: 0361-8773; 2168-815X
• DOI: 10.1007/bf02697982

Though free-radical emulsion polymerization has been studied extensively, published reports of cationic (i.e., acid-catalyzed) polymerizations of emulsified monomers are rare. It was recently discovered that treatment of an emulsion of liquid epoxy resin with select superacid catalysts yields a polymeric polyol. Catalysis with one percent perchloric acid at room temperature yields a product with a number average molecular weight of 1650, and a polydispersity of 5.0 as measured by GPC. The polyol's structure differs from that of conventional high molecular weight epoxy resins prepared by the advancement process in several ways, including the incorporation of two glycidyl units in the repeat unit. In essence, the product is a copolymer of the epoxy resin and water, in which water is incorporated in the repeat unit structure by reaction with two epoxide groups. A similar product can be prepared by solution polymerization, where the molecular weight is controlled by the ratio of water to epoxy resin. The product was shown to have lower levels of residual bisphenol-A than conventional advanced epoxy resins. Polyols prepared by these new processes were crosslinked fwith melamine-formaldehyde resins in waterborne coating formulations which were free of added cosolvent, as well as solventborne coating formulations. The coatings developed excellent solvent resistance at lower bake temperatures than traditional epoxy resins.