Tricrystalline TiO2 with enhanced photocatalytic activity and durability for removing volatile organic compounds from indoor air

• Published in: Journal of environmental sciences (China) Vol. 32; pp. 189 - 195
• Main Authors: Chen, Kunyang, Zhu, Lizhong, Yang, Kun
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01.06.2015
• Subjects: Air Pollutants - isolation & purification; Air Pollutants - radiation effects; Air Pollution, Indoor - analysis; Catalysis; Crystallization; Environmental Restoration and Remediation; Gaseous; Mesoporous; Nanomaterials; Oxidation-Reduction; Photocatalysis; Photochemical Processes; Titanium - chemistry; Toluene - isolation & purification; Tricrystalline TiO2; Ultraviolet Rays; VOC; Volatile Organic Compounds - isolation & purification; Volatile Organic Compounds - radiation effects; Nanomaterials; VOC; Mesoporous; Gaseous; Photocatalysis; Tricrystalline TiO2; Tricrystalline TiO
• ISSN: 1001-0742; 1878-7320
• DOI: 10.1016/j.jes.2014.10.023

It is important to develop efficient and economic techniques for removing volatile organic compounds (VOCs) in indoor air. Heterogeneous TiO2-based semiconductors are a promising technology for achieving this goal. Anatase/brookite/rutile tricrystalline TiO2 with mesoporous structure was synthesized by a low-temperature hydrothermal route in the presence of HNO3. The obtained samples were characterized by X-ray diffraction and N2 adsorption–desorption isotherm. The photocatalytic activity was evaluated by photocatalytic decomposition of toluene in air under UV light illumination. The results show that tricrystalline TiO2 exhibited higher photocatalytic activity and durability toward gaseous toluene than bicrystalline TiO2, due to the synergistic effects of high surface area, uniform mesoporous structure and junctions among mixed phases. The tricrystalline TiO2 prepared at RHNO3=0.8, containing 80.7% anatase, 15.6% brookite and 3.7% rutile, exhibited the highest photocatalytic activity, about 3.85-fold higher than that of P25. The high activity did not significantly degrade even after five reuse cycles. In conclusion, it is expected that our study regarding gas-phase degradation of toluene over tricrystalline TiO2 will enrich the chemistry of the TiO2-based materials as photocatalysts for environmental remediation and stimulate further research interest on this intriguing topic. [Display omitted]