Kinetics of SHS reactions: A review

The current state of chemical kinetics for self-propagating high-temperature non-catalytic reactions has been reviewed for results over the past 50 years. Five different characterization techniques are primarily considered: differential thermal analysis (DTA), electrothermal explosion (ETE), electro...

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Bibliographic Details
Published inInternational journal of self-propagating high-temperature synthesis Vol. 26; no. 3; pp. 145 - 165
Main Authors Mukasyan, A. S., Shuck, C. E.
Format Journal Article
LanguageEnglish
Published New York Allerton Press 01.07.2017
Springer Nature B.V
Subjects
Catalysis
Chemical reactions
Chemistry and Materials Science
Kinetics
Materials Science
Reaction kinetics
Self-propagating synthesis
Thermal analysis
kinetic parameters
combustion synthesis
experimental techniques
SHS
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Summary:The current state of chemical kinetics for self-propagating high-temperature non-catalytic reactions has been reviewed for results over the past 50 years. Five different characterization techniques are primarily considered: differential thermal analysis (DTA), electrothermal explosion (ETE), electrothermography (ET), combustion velocity/temperature analyses (Merzhanov–Khaikin and Boddington–Laye approaches), and other advanced in-situ diagnostics, including time-resolved X-ray diffraction (TRXRD). Based on the summary of results thus far, recommendations are given for the future of SHS kinetic research.
ISSN:1061-3862
1934-788X
DOI:10.3103/S1061386217030049