Spectral, morphological, linear and nonlinear optical properties of nanostructured benzimidazole metal complex thin films

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 150; pp. 280 - 289
• Main Authors: Praveen, P.A., Ramesh Babu, R., Jothivenkatachalam, K., Ramamurthi, K.
• Format: Journal Article
• Language: English
• Published: England Elsevier B.V 05.11.2015
• Subjects: Annealing; CW Z-scan; Metal organic thin films; Nonlinear optical properties; Optical limiting; Optical limiting; Annealing; Nonlinear optical properties; Metal organic thin films; CW Z-scan
• ISSN: 1386-1425; 1873-3557
• DOI: 10.1016/j.saa.2015.05.074

[Display omitted] •Computational studies ensure the potentiality of Benzimidazole metal complexes towards third order NLO applications.•Annealing improves the surface uniformity and reduces the optical scattering losses.•Thermal induced degradation of both the metal complex thin films have been observed by Raman spectroscopy. Metal organic materials are widely investigated to find their suitability for nonlinear optical applications due to the advantage of combined organic and inorganic properties. In this work benzimidazole based metal organic thin films of dichlorobis (1H-Benzimidazole) Co(II) and dichlorobis (1H-Benzimidazole) Cu(II) were deposited by chemical bath deposition method. The deposited films were annealed at 100, 150 and 200°C to investigate the effect of annealing on the properties of thin films. Surface homogeneity of the films was increased with the annealing temperature due to the surface diffusion of the films and the same was evidently shown by Raman spectroscopy and Atomic Force Microscopy studies. But annealing the films at 200°C yielded bulk patches on the surface due to the distortion of molecules. Linear and nonlinear optical properties of the films annealed at 150°C showed relatively higher transmittance and improved nonlinear optical properties than the other as prepared and annealed samples.