Microwave assisted synthesis, spectroscopic studies and non linear optical properties of bis-chromophores

• Published in: Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Vol. 137; pp. 1100 - 1105
• Main Authors: Khan, Salman A., Razvi, M.A.N., Bakry, Ahmed H., Afzal, S.M., Asiri, Abdullah M., El-Daly, Samy A.
• Format: Journal Article
• Language: English
• Published: England Elsevier B.V 25.02.2015
• Subjects: Bis-chromophore; Dimethyl Sulfoxide - chemistry; Dipole moment; Fluorescent Dyes - chemical synthesis; Fluorescent Dyes - chemistry; Microwaves; Nonlinear absorption; Oscillator strength; Spectrophotometry, Ultraviolet; Stokes shift; Oscillator strength; Stokes shift; Bis-chromophore; Nonlinear absorption; Dipole moment
• ISSN: 1386-1425; 1873-3557
• DOI: 10.1016/j.saa.2014.08.065

[Display omitted] •Synthesis of bis-chromophores by microwave irradiation.•Absorption and emission spectra of bis-chromophores in various non-polar, polar aprotic and protic solvents were studied.•Non linear optical properties of bis-chromophores. Bis chromophores were synthesized by the terephthalaldehyde with (4-nitrophenyl) acetonitrile/(4-flurophenyl) acetonitrile under microwave irradiation. Bis-chromophores were obtained in good to excellent yields. The structures of bis-chromophores were established by FT-IR, 1H NMR, 13C NMR, EI-MS and elemental analyses. Physical chemical properties such as singlet absorption, extinction coefficient, stokes shift, oscillator strength and dipole moment, were investigated by UV–Vis and fluorescence spectroscopy measurements. Further we also measured the nonlinear refractive index and nonlinear absorption coefficients of these compounds using the single beam z-scan technique with a cw argon ion laser at 514.5nm at different concentrations in DMSO solvent. The third order nonlinear susceptibility was estimated from these measurements and it shows high nonlinearity. The high negative refractive index makes these compounds suitable for optical limiting application.