Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes

The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I(2) and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and eta(2)-coordination to Zr. Addition of H(2) leads to both oxid...

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Published inChemical communications (Cambridge, England) Vol. 46; no. 31; pp. 5790 - 5792
Main Authors Thomas, Christine M, Napoline, J Wesley, Rowe, Gerard T, Foxman, Bruce M
Format Journal Article
LanguageEnglish
Published England 21.08.2010
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Summary:The reactivity of heterobimetallic Zr/Co complexes linked by phosphinoamide ligands towards the oxidative addition of I(2) and alkyl halides is reported. These reactions are accompanied by dissociation of one phosphine ligand from Co and eta(2)-coordination to Zr. Addition of H(2) leads to both oxidative addition across the M-M bond and P-N bond cleavage.
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ISSN:1359-7345
1364-548X
DOI:10.1039/c0cc01272f