Compton scattering studies of 4f ferromagnetism

• Published in: Radiation physics and chemistry (Oxford, England : 1993) Vol. 75; no. 11; pp. 1638 - 1645
• Main Authors: Cooper, M.J., Duffy, J.A., Banfield, Z.F., Bebb, A.M., Blaauw, L., Shenton-Taylor, C., Steer, C., Taylor, J.W.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.11.2006
• Subjects: Compton scattering; Ferromagnetism; Hexaborides; Rare earths; Ruthenates; Synchrotron radiation; Ferromagnetism; Compton scattering; Ruthenates; Rare earths; Hexaborides; Synchrotron radiation
• ISSN: 0969-806X; 1879-0895
• DOI: 10.1016/j.radphyschem.2005.07.034

Ferromagnetism can be studied in Compton scattering experiments, which use high-energy, elliptically polarised synchrotron radiation. The basis of the method and its interpretation in terms of site-specific moments will be explained and illustrated by a series of examples of archetypal compounds. For example, the hexaborides exhibit a wide range of electronic properties. Data will be presented for the heavy Fermion system CeB 6 and the controversial ferromagnet Ca 1− x La x B 6. Undoped CeB 6 exhibits a delocalised spin moment, more characteristic of the 5d than the 4f orbital. Whereas the magnetism in the Ca 1− x La x B 6 system has been suggested to be an extrinsic effect arising from iron contamination, our data indicate that the magnetism is intrinsic and inconsistent with what would be expected for an iron 3d moment. This supports the proposal that this system is, indeed, a weak itinerant ferromagnet. In Ru 2SrGdCu 20 8, we observe a combination of Gd 4f, Gd 5d and Ru 4d moments and the 5d moment appears to flip orientation below the Néel temperature.