Improved photocatalytic decolorization of reactive black 5 dye through synthesis of graphene quantum dots–nitrogen-doped TiO2

• Published in: Environmental science and pollution research international Vol. 30; no. 60; pp. 124992 - 125005
• Main Authors: Khan, Muhammad Saqib, Riaz, Nadia, Rehman, Saeed, Chenhui, Liu, Shaikh, Ahson Jabbar, Arfan, Muhammad, Zeb, Iftikhar, Arshad, Muhammad, Hafeez, Farhan, Bilal, Muhammad
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01.12.2023; Springer Nature B.V
• Subjects: Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Carbon-based Nanomaterials: Systematic Enumeration and Proficient Template for Detection and Remediation of Hazardous Pollutants; CI Reactive Black 5; Decoloring; Decolorization; Earth and Environmental Science; Ecotoxicology; Electromagnetic absorption; Electron transfer; Electrons; Energy levels; Environment; Environmental Chemistry; Environmental Health; Excitons; Graphene; Heterojunctions; Langmuir waves; Life span; Nanocomposites; Nitrogen; Oxygen; Particle size distribution; Photocatalysis; Quantum dots; Rate constants; Reactive oxygen species; Size distribution; Sol-gel processes; Substitution reactions; Surface reactions; Titanium dioxide; Waste Water Technology; Water Management; Water Pollution Control; Wavelengths; Photosensitizer; Type II heterojunction; Graphene quantum dots; Reaction kinetics; Heterogeneous reaction
• ISSN: 1614-7499; 0944-1344; 1614-7499
• DOI: 10.1007/s11356-023-28782-5

Graphene quantum dots (GQDs), a new solid-state electron transfer material was anchored to nitrogen-doped TiO 2 via sol gel method. The introduction of GQDs effectively extended light absorption of TiO 2 from UV to visible region. GQD-N-TiO 2 demonstrated lower PL intensity at excitation wavelengths of 320 to 450 nm confirming enhanced exciton lifespan. GQD-N-TiO 2 -300 revealed higher surface area (191.91m 2  g −1 ), pore diameter (1.94 nm), TEM particle size distribution (4.88 ± 1.26 nm) with lattice spacing of 0.45 nm and bandgap (2.91 eV). In addition, GQDs incorporation shifted XPS spectrum of Ti 2p to lower binding energy level (458.36 eV), while substitution of oxygen sites in TiO 2 lattice by carbon were confirmed through deconvolution of C 1 s spectrum. Photocatalytic reaction followed the pseudo first order reaction and continuous reductions in apparent rate constant ( K app ) with incremental increase in RB5 concentration. Langmuir–Hinshelwood model showed surface reaction rate constants K C  = 1.95 mg L −1  min −1 and K LH  = 0.76 L mg −1 . The active species trapping, and mechanism studies indicated the photocatalytic decolorization of RB5 through GQD-N-TiO 2 was governed by type II heterojunction. Overall, the photodecolorization reactions were triggered by the formation of holes and reactive oxygen species. The presence of •OH, 1 O 2 , and O 2 • during the photocatalytic process were confirmed through EPR analysis. The excellent photocatalytic decolorization of the synthesized nanocomposite against RB5 can be ascribed to the presence of GQDs in the TiO 2 lattice that acted as excellent electron transporter and photosensitizer. This study provides a basis for using nonmetal, abundant, and benign materials like graphene quantum dots to enhance the TiO 2 photocatalytic efficiency, opening new possibilities for environmental applications. Graphical Abstract