Extrusion Processed Polymer Electrolytes based on Poly(ethylene oxide) and Modified Sepiolite Nanofibers: Effect of Composition and Filler Nature on Rheology and Conductivity

• Published in: Electrochimica acta Vol. 137; pp. 526 - 534
• Main Authors: Mejía, Alberto, García, Nuria, Guzmán, Julio, Tiemblo, Pilar
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10.08.2014
• Subjects: Conductivity; Electrolyte; Poly(ethylene oxide); Rheology; Sepiolite; Conductivity; Poly(ethylene oxide); Electrolyte; Rheology; Sepiolite
• ISSN: 0013-4686; 1873-3859
• DOI: 10.1016/j.electacta.2014.06.032

•PEO/ethylene carbonate (EC)/LiTF electrolytes are prepared by extrusion.•Some include also sepiolite nanofibers with ad-hoc surface modifications.•Some of the electrolytes show σ>10−4 S cm−1 at RT and σ> 10−3 S cm−1 at T>50°C.•One of them, with EC and one of the nanofibers, is solid-like between 50-90°C.•Both high σ and mechanical performance are stable for long periods of time. A series of poly(ethylene oxide) (PEO)/lithium trifluoromethanesulfonate(LiTf)/ethylene carbonate(EC)/sepiolite composite electrolytes have been prepared by melt compounding. Neat sepiolite, sepiolite coated with polyethylene glycol and with D-α-tocopherol polyethylene glycol 1000 succinate have been used as fillers, and nanocomposites with different ratio of the components have been prepared. The concentration of EC and LiTf has been progressively increased from low to high values and in this way, electrolytes with conductivities from 2×10−6 to 3×10−4 S cm−1 at 30°C have been prepared. Together with conductivity, viscoelasticity has also been studied, evidencing a complex rheological behaviour which depends on the type of filler introduced in the blend. Some of the thermoplastic electrolytes are seen to display a liquid-like conductivity together with solid-like mechanical properties over the melting point of PEO. The solid-like performance is featured by shear moduli crossover G’=G” at 75°C at very low frequencies. This combination of properties makes them appealing starting points for the development of solid polymer electrolytes.