Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant

A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp(3) C-H and sp(3) C-H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, beta-keto esters and malononitrile are active participants in this coupling...

Full description

Saved in:
Bibliographic Details
Published inOrganic & biomolecular chemistry Vol. 8; no. 18; pp. 4077 - 4079
Main Authors Shu, Xing-Zhong, Yang, Yan-Fang, Xia, Xiao-Feng, Ji, Ke-Gong, Liu, Xue-Yuan, Liang, Yong-Min
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 21.09.2010
Subjects
Alkanes - chemistry
Catalysis
Chemistry
Chemistry, Organic
Esters - chemistry
Hydrogenation
Ketones - chemical synthesis
Ketones - chemistry
Molecular Structure
Nitriles - chemistry
Nitro Compounds - chemistry
Oxidation-Reduction
Physical Sciences
Platinum - chemistry
Science & Technology
Stereoisomerism
FUNCTIONALIZATION
ORGANIC-SYNTHESIS
SP C-H
TERTIARY-AMINES
NITROGEN ATOM
SODIUM-CYANIDE
BOND ACTIVATION
HYDROGEN-PEROXIDE
OXIDATIVE CYANATION
MOLECULAR-OXYGEN
Online AccessGet full text

Cover

More Information
Summary:A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp(3) C-H and sp(3) C-H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, beta-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1477-0520
1477-0539
DOI:10.1039/c0ob00261e