Self-assembled ultrathin NiCo2S4 nanoflakes grown on Ni foam as high-performance flexible electrodes for hydrogen evolution reaction in alkaline solution

• Published in: Nano energy Vol. 24; pp. 139 - 147
• Main Authors: Ma, Lianbo, Hu, Yi, Chen, Renpeng, Zhu, Guoyin, Chen, Tao, Lv, Hongling, Wang, Yanrong, Liang, Jia, Liu, Haixia, Yan, Changzeng, Zhu, Hongfei, Tie, Zuoxiu, Jin, Zhong, Liu, Jie
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01.06.2016
• Subjects: Alkaline solution; Hydrogen evolution reaction; Layered double hydroxide; Three-dimensional-networked structure; Ultrathin NiCo2S4 nanoflakes; Hydrogen evolution reaction; Alkaline solution; Ultrathin NiCo2S4 nanoflakes; Layered double hydroxide; Three-dimensional-networked structure
• ISSN: 2211-2855
• DOI: 10.1016/j.nanoen.2016.04.024

Considerable efforts have been devoted on the design and fabrication of non-platinum electrocatalysts with high performance and low cost for hydrogen evolution reaction (HER). However, the catalytic activity of existing electrocatalysts usually subjects to the limited amount of exposed active sites. Herein, we propose that self-assembled ultrathin NiCo2S4 nanoflakes grown on nickel foam (NiCo2S4/Ni foam) can serve as excellent electrocatalyst for HER in alkaline solution with high activity and stability. The NiCo2S4/Ni foam electrodes were prepared by the complete sulfidation of networked ultrathin NiCo-layered double hydroxide nanoflakes grown on Ni foam (NiCo-LDH/Ni foam). The advantages of this unique architecture are that the ultrathin and porous NiCo2S4 nanoflakes can provide a huge number of exposed active sites, the highly-conductive Ni foam can promote the transfer of electrons, and the three-dimensional-networked structure can facilitate the diffusion and penetration of electrolyte. Electrochemical measurements reveal that NiCo2S4/Ni foam electrodes exhibit greatly improved performance than NiCo-LDH/Ni foam for HER in alkaline solution with low onset overpotential (17mV), small Tafel slope (84.5mV/dec) and excellent long-duration cycling stability (maintaining an onset overpotential of ~20mV and an overpotential of 155mV at 50mA/cm2 after testing for 100,000s). In addition, the highly-flexible NiCo2S4/Ni foam electrodes show no obvious catalytic degradation after bending for 200 times, confirming the high flexibility and robustness under severe conditions. [Display omitted] •Self-assembled ultrathin NiCo2S4 nanoflakes grown on Ni foam was fabricated.•NiCo2S4/Ni foam was prepared by directly sulfidation of NiCo-LDH/Ni foam.•NiCo2S4/Ni foam show a significantly improved HER catalytic activity.•Possible mechanism for the enhanced catalytic activity was proposed.