Fe-pyridinedicarboxylate based coordination polymer nanorods as a heterogeneous Fenton catalyst for pollutant degradation

A Fe-pyridinedicaroxylate based coordination polymer with a monodisperse morphology of nanorods was synthesized under solvothermal conditions. This compound could work as a heterogeneous Fenton catalyst to degrade a series of organic pollutants, and exhibited high activity, good stability, a wide pH...

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Bibliographic Details
Published inRSC advances Vol. 6; no. 72; pp. 68227 - 6823
Main Authors Li, Wen-Juan, Liu, Huan, Guo, An, Chang, Lan, Yao, Xi-Yuan, Sun, Bi-Zhu, Meng, Jia-Lin, Li, Yue, Ruan, Wen-Juan
Format Journal Article
LanguageEnglish
Published 01.01.2016
Subjects
Catalysts
Coordination polymers
Degradation
hydrogen peroxide
Nanorods
Pollutants
Stability
Tolerances
Utilization
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Summary:A Fe-pyridinedicaroxylate based coordination polymer with a monodisperse morphology of nanorods was synthesized under solvothermal conditions. This compound could work as a heterogeneous Fenton catalyst to degrade a series of organic pollutants, and exhibited high activity, good stability, a wide pH tolerance and efficient H 2 O 2 utilization in the reactions. A Fe-pyridinedicaroxylate based nanoscale coordination polymer works as a Fenton catalyst to degrade pollutants by the formation of &z.rad;OH and high-valent iron species.
Bibliography:Electronic supplementary information (ESI) available: Experimental details, PXRD pattern, FT-IR spectrum, XPS spectrum, N
p
2
10.1039/c6ra13556k
H
2+
and Fe
condutions. See DOI
chlorophenol, methylene blue, methyl orange and rhodamine B with Fe-pydc catalysis, and phenol degradation under FeO/H
adsorption-desorption isotherm and TGA curve of Fe-pydc, characterization results of the used catalyst, degradation kinetics of benzoic acid
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ISSN:2046-2069
2046-2069
DOI:10.1039/c6ra13556k