Role of solvents in coordination supramolecular systems

Solvent effect is a vital subject in the domain of coordination chemistry. In this connection, previous researches mainly focus on the role of solvents in reaction kinetics and thermodynamics during the coordination processes. In virtue of the recent efforts on coordination supramolecular systems, e...

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Bibliographic Details
Published inChemical communications (Cambridge, England) Vol. 47; no. 21; pp. 5958 - 5972
Main Authors Li, Cheng-Peng, Du, Miao
Format Journal Article
LanguageEnglish
Published England 01.01.2011
Subjects
Assembly
chemical communication
chemical reactions
coordination polymers
Crystal growth
Dynamical systems
Dynamics
Modulation
reaction kinetics
Solvent effect
Solvents
thermodynamics
Transformations
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Summary:Solvent effect is a vital subject in the domain of coordination chemistry. In this connection, previous researches mainly focus on the role of solvents in reaction kinetics and thermodynamics during the coordination processes. In virtue of the recent efforts on coordination supramolecular systems, especially coordination polymers or metal-organic frameworks, this feature article aims to demonstrate the solvent effect on regulating such diversiform metallosupramolecular solids, incorporating their crystal growth/assembly, structural modulation, dynamic transformations, and potential applications, which may provide new insights into the rational design and construction of such advanced crystalline materials.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/c1cc10935a