Stabilization of ZnS nanoparticles by polymeric matrices: syntheses, optical properties and recent applications

ZnS has been one of the most investigated II-IV semiconductor materials, known for very interesting optoelectronic properties and its versatile applications in various fields. The transition from bulk to nano regime has brought forth some drastic changes in the optical properties of ZnS. In this rev...

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Bibliographic Details
Published inRSC advances Vol. 6; no. 69; pp. 644 - 6442
Main Authors Tiwari, Ashish, Dhoble, S. J
Format Journal Article
LanguageEnglish
Published 01.01.2016
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Summary:ZnS has been one of the most investigated II-IV semiconductor materials, known for very interesting optoelectronic properties and its versatile applications in various fields. The transition from bulk to nano regime has brought forth some drastic changes in the optical properties of ZnS. In this review article, we have comprehensively discussed the surface passivation of ZnS nanoparticles by various polymeric ligands/matrix. Systematic investigation has been reported for state of the art synthesis and novel strategies for fabrication of ZnS nanocomposites have been discussed. A brief account of the pioneer works for ZnS has been described and their fundamental properties have been discussed. The characterization techniques in understanding the formation and stabilization of ZnS nanocomposites are highlighted. The article primarily focuses on the main features, synthesis techniques, and optical properties of polymer based ZnS nanocomposites. We have tried to cover recent application and developments in field of polymer based ZnS nanocomposites in biosensing, cell tagging, optoelectronic devices, heterogeneous catalysis, photocatalytic application etc. Overall this article provides an insight to optimize the synthetic routes and condition for better utilization of ZnS nanocomposites and provide an outlook to expand these applications to other areas, such as drug delivery, labeling, tracking agents, bioanalytical sensors, fluorescent probes, optics, information storage, and optoelectronics. ZnS nanocomposites is a promising area of research for designing novel functional hybrid materials due to their unique optical and electronic properties. This review emphasizes on the synthesis, optical studies and potential applications.
Bibliography:S. J. Dhoble obtained his Ph.D. degree from RTM Nagpur University, Nagpur, India in 1992. He is presently working as an Associate Professor in Department of Physics, R.T.M. Nagpur University, Nagpur, India. He has published more than 500 articles. He serves as an editor of Luminescence: The Journal of Biological and Chemical Luminescence, John Wiley & Sons Ltd. Publication. He is recipient of Prof. B.T.Deshmukh Research Award 2016 and Prof. B.P.Chandra Research Award 2016, Outstanding Scientist-2015, form Venus International Foundation and Advanced Materials Scientist Letter Awards-2011 for outstanding contribution in Advanced Materials Letter. His current research interests are synthesis of solid state lighting nanomaterials and radiation dosimetry phosphors.
Ashish Tiwari received his Ph. D degree from Guru Ghasidas Vishwavidhyalaya: A Central University, Bilaspur, India in 2012. The topic of his PhD dissertation was Luminescence properties of ZnS nanophosphors using different capping molecules. He is currently working as an Assistant Professor in Department of Chemistry, in Government Lahiri College Chirmiri, India. He is recipient of Young Scientist Award from Chhattisgarh Council of Science & Technology (CCOST) in 2012. His current research interest is synthesis of luminescent nanomaterials.
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ISSN:2046-2069
2046-2069
DOI:10.1039/c6ra13108e