Oxygen-defective Co3O4 for pseudo-capacitive lithium storage

• Published in: Journal of power sources Vol. 439; p. 227026
• Main Authors: Zhang, Jie, Jiang, Heng, Zeng, Yibo, Zhang, Ying, Guo, Hang
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01.11.2019
• Subjects: Lithium ion batteries; Oxygen vacancy; Transiton metal oxide; Lithium ion batteries; Transiton metal oxide; Oxygen vacancy
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2019.227026

Transition metal oxide is widely studied type of high-capacity anode material for lithium ion batteries. Herein, oxygen-defective cobalt oxide with attractive lithium storage performance is prepared via a two-step strategy. Experimental results shows that there is certain amount of oxygen vacancies in Co3O4. Reversible conversion between metallic Co and CoO during the charge-discharge process was revealed by ex-situ XRD. Reversible morphology evolution is also confirmed by the ex-situ FE-SEM. The oxygen-defective Co3O4 anode shows attractive stability and rate performance. It possesses a discharge capacity of 1006 mAh∙g−1 in the first cycle, with a high initial Coulombic efficiency of 73.9%. A reversible capacity of 896 mAh∙g−1 can be maintained after 200 cycles at 250 mA g−1. It could even stably operate at an elevated current density of 5000 mA g−1 for 500 times. Further kinetic analysis reveals that pseudo-capacitance plays a dominant role in the lithium storage of oxygen-defective Co3O4. Existence of oxygen vacancies could not only facilitate Li+ migration but also enhance electric conductivity to a certain extent, resulting in improved lithium storage performance. •Oxygen-defective Co3O4 anode was prepared via a facile coordination strategy.•Phase and morphology evolution of Co3O4 were revealed by ex-situ characterization.•Lithium storage in Co3O4 is dominated by a pseudo-capacitance controlled process.