Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials

The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4'-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-f...

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Published inChemical communications (Cambridge, England) Vol. 55; no. 23; pp. 3367 - 3370
Main Authors Mohmeyer, Alexander, Schaate, Andreas, Hoppe, Bastian, Schulze, Hendrik A, Heinemeyer, Thea, Behrens, Peter
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 14.03.2019
Subjects
Composite materials
Electrical resistivity
Grafting
Metal-organic frameworks
Prepolymers
Zirconium
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Summary:The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4'-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications.
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content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/c8cc10298h