Direct grafting-from of PEDOT from a photoreactive Zr-based MOF - a novel route to electrically conductive composite materials
The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4'-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-f...
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Published in | Chemical communications (Cambridge, England) Vol. 55; no. 23; pp. 3367 - 3370 |
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Main Authors | , , , , , |
Format | Journal Article |
Language | English |
Published |
England
Royal Society of Chemistry
14.03.2019
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Subjects | |
Online Access | Get full text |
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Summary: | The postsynthetic potential of the two-dimensional metal-organic framework Zr-bzpdc-MOF which is based on the photoreactive molecule benzophenone-4,4'-dicarboxylic acid (H2bzpdc) is used here to selectively functionalize the MOF surface. We report the direct radical-induced oxidative grafting-from polymerization of the precursor EDOT on Zr-bzpdc-MOF, leading to an electrically conductive composite material and opening the road to a variety of applications. |
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Bibliography: | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1359-7345 1364-548X |
DOI: | 10.1039/c8cc10298h |