Challenges and prospects of polyatomic ions' intercalation in the graphite layer for energy storage applications
Global population explosion has led to the rapid revolution of science and technology, and the high energy demand has necessitated new and efficient energy conversion and storage systems. Lithium ion batteries (LIBs) have a high potential window, high capacity, and high stability, but suffer from hi...
Saved in:
Published in | Physical chemistry chemical physics : PCCP Vol. 22; no. 43; pp. 24842 - 24855 |
---|---|
Main Authors | , , |
Format | Journal Article |
Language | English |
Published |
Cambridge
Royal Society of Chemistry
21.11.2020
|
Subjects | |
Online Access | Get full text |
Cover
Loading…
Summary: | Global population explosion has led to the rapid revolution of science and technology, and the high energy demand has necessitated new and efficient energy conversion and storage systems. Lithium ion batteries (LIBs) have a high potential window, high capacity, and high stability, but suffer from high cost and low safety. Therefore, many alternative batteries, including sodium ion batteries (NIBs), potassium (KIBs), aluminum (AIBs), and dual ion batteries (DIBs), have been introduced. One of the key working principles of these batteries is based on cation or anion intercalation in the graphite layers, and leads to the formation of graphite intercalation compounds (GICs). Recently, studies based on determining a reaction mechanism to improve the performance of the batteries have been conducted. In this review, an overview of the work on the reaction mechanism of polyatomic ions intercalated into GICs, the structure of intercalated polyatomic ions, the structure of the accommodated GICs, and their staging is provided. In other words, this review focuses on unraveling and understanding the reaction mechanisms for the intercalation of polyatomic ions into GICs by
in situ
and
ex situ
techniques, correlated with computational studies. The current limitations and future prospects of polyatomic ions intercalation batteries are also discussed.
This review focuses on unraveling the reaction mechanisms of the intercalation of polyatomic ions into GICs by
in situ
techniques, correlated with computational studies. |
---|---|
Bibliography: | Ms Hsiang-Ju Liao received her bachelor's degree from the Department of Chemistry in National Taiwan Normal University in 2016. She worked as a research assistant in Prof. Di-Yan Wang's lab in Tunghai University from 2016 to 2017. In 2019, she received her master's degree from the Department of Materials Science and Engineering in National Tsing-Hua University, Taiwan. Her research interests focus on dual-ion batteries and zinc-ion batteries. Mr Shivaraj B. Patil received his bachelor's degree from Karnataka University, India, in 2014. In 2016, he received his master's degree from Christ University, India. He is currently pursuing a PhD degree in chemistry at Tunghai University, Taiwan. His current research interests include electrocatalytic catalysis and energy storage systems. Dr Di-Yan Wang is currently an associate professor at the Department of Chemistry, Tunghai University from 2016 to the present. His research focuses on developing new type 2D materials for catalytic activity, photoenergy and battery application fields, and investigating the related reaction mechanisms by using operando synchrotron and Raman techniques. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
ISSN: | 1463-9076 1463-9084 |
DOI: | 10.1039/d0cp04098c |