Tetrakis(thiourea-κ S )palladium(II) dithiocyanate
The title compound, [Pd(CH4N2S)4](SCN)2, consists of complex [Pd(TU)4]2+ [TU = thiourea, SC(NH2)2] cations and thiocyanate counter-anions. The PdII cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are co...
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Published in | Acta crystallographica. Section E, Structure reports online Vol. 64; no. 5; pp. m698 - m699 |
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Main Authors | , , , , |
Format | Journal Article |
Language | English |
Published |
International Union of Crystallography
01.05.2008
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Online Access | Get full text |
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Summary: | The title compound, [Pd(CH4N2S)4](SCN)2, consists of complex [Pd(TU)4]2+ [TU = thiourea, SC(NH2)2] cations and thiocyanate counter-anions. The PdII cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thiocyanate ions via N-H...N [2.922 (3)-3.056 (3) Å] and N-H...S [3.369 (2)-3.645 (2) Å] hydrogen bonds. |
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ISSN: | 1600-5368 1600-5368 |
DOI: | 10.1107/S160053680801088X |