Tetrakis(thiourea-κ S )palladium(II) dithiocyanate

The title compound, [Pd(CH4N2S)4](SCN)2, consists of complex [Pd(TU)4]2+ [TU = thiourea, SC(NH2)2] cations and thiocyanate counter-anions. The PdII cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are co...

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Published inActa crystallographica. Section E, Structure reports online Vol. 64; no. 5; pp. m698 - m699
Main Authors Nadeem, Shafqat, Khawar Rauf, M., Ebihara, Masahiro, Tirmizi, Syed Ahmed, Ahmad, Saeed
Format Journal Article
LanguageEnglish
Published International Union of Crystallography 01.05.2008
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Summary:The title compound, [Pd(CH4N2S)4](SCN)2, consists of complex [Pd(TU)4]2+ [TU = thiourea, SC(NH2)2] cations and thiocyanate counter-anions. The PdII cation is situated on an inversion centre and exhibits an almost square-planar coordination by the S atoms of the TU ligands. The complex cations are connected through the thiocyanate ions via N-H...N [2.922 (3)-3.056 (3) Å] and N-H...S [3.369 (2)-3.645 (2) Å] hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053680801088X