A fluorous synthetic receptor that recognizes perfluorooctanoic acid (PFOA) via fluorous interaction obtained by molecular imprinting

A polymeric sorbent selective for perfluorooctanoic acid (PFOA) was synthesized by a molecular imprinting technique using a fluorous monomer and cross-linker, and assessed chromatographically, suggesting that the fluorous imprinted polymer recognizes PFOA via hydrogen bonding and fluorine-fluorine i...

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Bibliographic Details
Published inAnalyst (London) Vol. 137; no. 12; pp. 2762 - 2765
Main Authors TAKAYOSE, Megumi, NISHIMOTO, Kenji, MATSUI, Jun
Format Journal Article
LanguageEnglish
Published Cambridge Royal Society of Chemistry 21.06.2012
Subjects
Analytical chemistry
Caprylates - analysis
Caprylates - chemistry
Chemistry
Chromatography
Chromatography, Liquid
Exact sciences and technology
Fluorine - chemistry
Fluorocarbons - analysis
Fluorocarbons - chemistry
Hydrogen bonding
Imprinted polymers
Molecular imprinting
Molecular Imprinting - methods
Monomers
Polymers - chemical synthesis
Polymers - chemistry
Receptors
Recognition
Solvents - chemistry
Sorption
Molecular structure
Fluorine
Hydrogen
Polymer
Technique
Molecular imprinting
Chemical enrichment
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Summary:A polymeric sorbent selective for perfluorooctanoic acid (PFOA) was synthesized by a molecular imprinting technique using a fluorous monomer and cross-linker, and assessed chromatographically, suggesting that the fluorous imprinted polymer recognizes PFOA via hydrogen bonding and fluorine-fluorine interaction.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0003-2654
1364-5528
DOI:10.1039/c2an15936h