Tuning the Circular Dichroism and Circular Polarized Luminescence Intensities of Chiral 2D Hybrid Organic–Inorganic Perovskites through Halogenation of the Organic Ions
Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid organic–inorganic perovskites (HOIPs) are investigated. Among them, the HOIP having a Cl‐substituted chiral cation exhibits the highest circular di...
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| Published in | Angewandte Chemie International Edition Vol. 60; no. 39; pp. 21434 - 21440 |
|---|---|
| Main Authors | , , , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
Weinheim
Wiley Subscription Services, Inc
20.09.2021
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| Edition | International ed. in English |
| Subjects | |
| Online Access | Get full text |
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| Abstract | Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid organic–inorganic perovskites (HOIPs) are investigated. Among them, the HOIP having a Cl‐substituted chiral cation exhibits the highest circular dichroism (CD) and circular polarized luminescence (CPL) intensities, indicating the existence of the largest rotatory strength, whereas the F‐substituted HIOP shows the weakest intensities. The observed modulation can be correlated to the varied magnetic transition dipole of HOIPs, which is sensitive to the d‐spacing between inorganic layers and the halogen–halogen interaction between organic cations and the inorganic sheets. These counteracting effects meet the optimal CD and CPL intensity with chlorine substitution, rendering the rotatory strength of HOIPs arranged in the order of (ClMBA)2PbI4>(BrMBA)2PbI4>(IMBA)2PbI4>(MBA)2PbI4>(FMBA)2PbI4.
Through the incorporation of Cl‐substituted chiral organic cations, the chiroptical properties of 2D chiral perovskites can be significantly enhanced. The observed circular dichroism and circular polarized luminescence intensities are found to be associated with the d‐spacing of hybrid organic–inorganic perovskites and the strength of the halogen–halogen interaction within the system. |
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| AbstractList | Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid organic–inorganic perovskites (HOIPs) are investigated. Among them, the HOIP having a Cl‐substituted chiral cation exhibits the highest circular dichroism (CD) and circular polarized luminescence (CPL) intensities, indicating the existence of the largest rotatory strength, whereas the F‐substituted HIOP shows the weakest intensities. The observed modulation can be correlated to the varied magnetic transition dipole of HOIPs, which is sensitive to the d‐spacing between inorganic layers and the halogen–halogen interaction between organic cations and the inorganic sheets. These counteracting effects meet the optimal CD and CPL intensity with chlorine substitution, rendering the rotatory strength of HOIPs arranged in the order of (ClMBA)
2
PbI
4
>(BrMBA)
2
PbI
4
>(IMBA)
2
PbI
4
>(MBA)
2
PbI
4
>(FMBA)
2
PbI
4
. Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid organic–inorganic perovskites (HOIPs) are investigated. Among them, the HOIP having a Cl‐substituted chiral cation exhibits the highest circular dichroism (CD) and circular polarized luminescence (CPL) intensities, indicating the existence of the largest rotatory strength, whereas the F‐substituted HIOP shows the weakest intensities. The observed modulation can be correlated to the varied magnetic transition dipole of HOIPs, which is sensitive to the d‐spacing between inorganic layers and the halogen–halogen interaction between organic cations and the inorganic sheets. These counteracting effects meet the optimal CD and CPL intensity with chlorine substitution, rendering the rotatory strength of HOIPs arranged in the order of (ClMBA)2PbI4>(BrMBA)2PbI4>(IMBA)2PbI4>(MBA)2PbI4>(FMBA)2PbI4. Through the incorporation of Cl‐substituted chiral organic cations, the chiroptical properties of 2D chiral perovskites can be significantly enhanced. The observed circular dichroism and circular polarized luminescence intensities are found to be associated with the d‐spacing of hybrid organic–inorganic perovskites and the strength of the halogen–halogen interaction within the system. Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid organic–inorganic perovskites (HOIPs) are investigated. Among them, the HOIP having a Cl‐substituted chiral cation exhibits the highest circular dichroism (CD) and circular polarized luminescence (CPL) intensities, indicating the existence of the largest rotatory strength, whereas the F‐substituted HIOP shows the weakest intensities. The observed modulation can be correlated to the varied magnetic transition dipole of HOIPs, which is sensitive to the d‐spacing between inorganic layers and the halogen–halogen interaction between organic cations and the inorganic sheets. These counteracting effects meet the optimal CD and CPL intensity with chlorine substitution, rendering the rotatory strength of HOIPs arranged in the order of (ClMBA)2PbI4>(BrMBA)2PbI4>(IMBA)2PbI4>(MBA)2PbI4>(FMBA)2PbI4. |
| Author | Chiu, Ching‐Wen Chou, Pi‐Tai Yang, Lan‐Sheng Lin, Tai‐Chun Liu, Yi‐Hung Lin, Jin‐Tai Chen, Deng‐Gao Chao, Yu‐Chiang |
| Author_xml | – sequence: 1 givenname: Jin‐Tai surname: Lin fullname: Lin, Jin‐Tai organization: National Taiwan University – sequence: 2 givenname: Deng‐Gao orcidid: 0000-0001-6406-2209 surname: Chen fullname: Chen, Deng‐Gao organization: National Taiwan University – sequence: 3 givenname: Lan‐Sheng orcidid: 0000-0001-9211-458X surname: Yang fullname: Yang, Lan‐Sheng organization: National Taiwan Normal University – sequence: 4 givenname: Tai‐Chun surname: Lin fullname: Lin, Tai‐Chun organization: National Taiwan University – sequence: 5 givenname: Yi‐Hung surname: Liu fullname: Liu, Yi‐Hung organization: National Taiwan University – sequence: 6 givenname: Yu‐Chiang orcidid: 0000-0002-9831-9292 surname: Chao fullname: Chao, Yu‐Chiang email: ycchao@ntnu.edu.tw organization: National Taiwan Normal University – sequence: 7 givenname: Pi‐Tai orcidid: 0000-0002-8925-7747 surname: Chou fullname: Chou, Pi‐Tai email: chop@ntu.edu.tw organization: National Taiwan University – sequence: 8 givenname: Ching‐Wen orcidid: 0000-0001-7201-0943 surname: Chiu fullname: Chiu, Ching‐Wen email: cwchiu@ntu.edu.tw organization: National Taiwan University |
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| Snippet | Through the incorporation of various halogen‐substituted chiral organic cations, the effects of chiral molecules on the chiroptical properties of hybrid... |
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| SubjectTerms | Cations chirality Chlorine Circular dichroism circular polarized luminescence Dichroism Dipoles Halogenation Luminescence Magnetic transitions Perovskites rotatory strength Substitutes |
| Title | Tuning the Circular Dichroism and Circular Polarized Luminescence Intensities of Chiral 2D Hybrid Organic–Inorganic Perovskites through Halogenation of the Organic Ions |
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