Fast hydrogen diffusion induced by hydrogen pre-split for gasochromic based optical hydrogen sensors

• Published in: International journal of hydrogen energy Vol. 44; no. 29; pp. 15665 - 15676
• Main Authors: Wang, Haoran, Gao, Guohua, Wu, Guangming, Zhao, Huiyue, Qi, Wanyu, Chen, Kaicong, Zhang, Wan, Li, Yunyun
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 07.06.2019
• Subjects: Diffusion; Gasochromic; Hydrogen sensor; Sol-gel; Hydrogen sensor; Gasochromic; Diffusion; Sol-gel
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2019.04.026

Gasochromic based optical hydrogen sensors have attracted much attention as normal temperature sensors. The behaviors of the hydrogen diffusion largely affect the reaction process and the sensitivity. However, few researches focused on the influence of hydrogen diffusion in gasochromic films. Here, we report a method to pre-split the H2 molecule and separate the hydrogen molecule and hydrogen atom diffusion process by deposition of porous PdCl2/SiO2 catalyst films on WO3. The response time of WO3 at 844 Pa H2 partial pressure reduced from 800 s to 200 s. The stability of WO3 film was largely improved to be more than 160 cycling lifetime. A validation experiment was designed and proved the diffusion of the hydrogen atom and the two-step model of H2 reaction on WO3 films, on the basis of which the diffusion coefficient of the hydrogen atom has been estimated. Moreover, the PdCl2 doping SiO2 catalyst exhibits substrate versatility, which can also coat on the nano-structured WO3. •WO3 gasochromic sensor with uniform silica catalyst support was prepared.•The H2 was split into H atom where a faster diffusion can be achieved.•The sensor is capable of detecting H2 below 844 Pa H2 partial pressure in 200 s.