Nitrogen doped lotus stem carbon as electrocatalyst comparable to Pt/C for oxygen reduction reaction in alkaline media

• Published in: International journal of hydrogen energy Vol. 42; no. 32; pp. 20560 - 20567
• Main Authors: Weththasinha, H.A.B.M.D., Yan, Zaoxue, Gao, Lina, Li, Yuan, Pan, Denghui, Zhang, Mingmei, Lv, Xiaomeng, Wei, Wei, Xie, Jimin
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 10.08.2017
• Subjects: Lotus stem; Nitrogen doped porous carbon; Oxygen reduction reaction; Pyridine N; Nitrogen doped porous carbon; Lotus stem; Pyridine N; Oxygen reduction reaction
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2017.06.011

The nitrogen doped carbon with high content of pyridine N and porous structure indicates high activity for oxygen reduction reaction (ORR). In this paper, nitrogen doped lotus stem carbon (N-LSC) with 6.3 at% of N (containing 52 at% of pyridine N) and porous structure is developed by using lotus stem as carbon source and dopamine hydrochloride as nitrogen source. The ORR activity, stability and methanol tolerance are characterized. The results show that the N-LSC has comparable activity to Pt/C, and much better methanol tolerance and stability than Pt/C. The porous structure and high content of pyridine N are believed to lead to the high ORR performances of the N-LSC. •Mesoporous N doped lotus stem carbon (N-LSC) is synthesized.•The N-LSC has 6.3 at% of N containing 52 at% of pyridine N.•The N-LSC shows comparable ORR activity to Pt/C.