Tetrathiafulvalene-based radical cation salts with transition metal bis(dicarbollide) anions
Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewe...
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| Published in | CrystEngComm Vol. 17; no. 26; pp. 4754 - 4767 |
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| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
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01.01.2015
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| Abstract | Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewed. The effect of various substituents in the metallacarborane anion on the structure and physical properties of their tetrathiafulvalene-based radical cation salts was analyzed. Relationships between the crystal structure and properties of the tetrathiafulvalene-based radical cation salts containing sandwiched transition metal bis(1,2-dicarbollide) anions are discussed.
Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. |
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| AbstractList | Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewed. The effect of various substituents in the metallacarborane anion on the structure and physical properties of their tetrathiafulvalene-based radical cation salts was analyzed. Relationships between the crystal structure and properties of the tetrathiafulvalene-based radical cation salts containing sandwiched transition metal bis(1,2-dicarbollide) anions are discussed. Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewed. The effect of various substituents in the metallacarborane anion on the structure and physical properties of their tetrathiafulvalene-based radical cation salts was analyzed. Relationships between the crystal structure and properties of the tetrathiafulvalene-based radical cation salts containing sandwiched transition metal bis(1,2-dicarbollide) anions are discussed. Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. |
| Author | Sivaev, Igor B Kazheva, Olga N Dyachenko, Oleg A Starodub, Vladimir A Bregadze, Vladimir I Kravchenko, Andrey V |
| AuthorAffiliation | Department of Chemistry Instytut Chemii Russian Academy of Sciences A. N. Nesmeyanov Institute of Organoelement Compounds V. N. Karazin Kharkiv National University Uniwersytet Jana Kochanowskiego Institute of Problems of Chemical Physics |
| AuthorAffiliation_xml | – name: Department of Chemistry – name: Russian Academy of Sciences – name: A. N. Nesmeyanov Institute of Organoelement Compounds – name: Uniwersytet Jana Kochanowskiego – name: Instytut Chemii – name: Institute of Problems of Chemical Physics – name: V. N. Karazin Kharkiv National University |
| Author_xml | – sequence: 1 givenname: Vladimir I surname: Bregadze fullname: Bregadze, Vladimir I – sequence: 2 givenname: Oleg A surname: Dyachenko fullname: Dyachenko, Oleg A – sequence: 3 givenname: Olga N surname: Kazheva fullname: Kazheva, Olga N – sequence: 4 givenname: Andrey V surname: Kravchenko fullname: Kravchenko, Andrey V – sequence: 5 givenname: Igor B surname: Sivaev fullname: Sivaev, Igor B – sequence: 6 givenname: Vladimir A surname: Starodub fullname: Starodub, Vladimir A |
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| Snippet | Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the... |
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| SubjectTerms | Anions Cations Crystal structure Derivatives Magnetic properties Physical properties Radicals Transition metals |
| Title | Tetrathiafulvalene-based radical cation salts with transition metal bis(dicarbollide) anions |
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