Tetrathiafulvalene-based radical cation salts with transition metal bis(dicarbollide) anions

Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewe...

Full description

Saved in:
Bibliographic Details
Published inCrystEngComm Vol. 17; no. 26; pp. 4754 - 4767
Main Authors Bregadze, Vladimir I, Dyachenko, Oleg A, Kazheva, Olga N, Kravchenko, Andrey V, Sivaev, Igor B, Starodub, Vladimir A
Format Journal Article
LanguageEnglish
Published 01.01.2015
Subjects
Anions
Cations
Crystal structure
Derivatives
Magnetic properties
Physical properties
Radicals
Transition metals
Online AccessGet full text

Cover

More Information
Summary:Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials. The data on their synthesis, crystal structure, and electrical and magnetic properties were reviewed. The effect of various substituents in the metallacarborane anion on the structure and physical properties of their tetrathiafulvalene-based radical cation salts was analyzed. Relationships between the crystal structure and properties of the tetrathiafulvalene-based radical cation salts containing sandwiched transition metal bis(1,2-dicarbollide) anions are discussed. Radical cation salts based on derivatives of tetrathiafulvalene and sandwiched transition metal bis(dicarbollide) anions are of great interest in the development of new molecular conducting materials.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1466-8033
1466-8033
DOI:10.1039/c5ce00835b