Effect of calcination temperature on hydrophobicity of microporous layers prepared with two different molecular weights of PDMS polymer on PEM fuel cell performance with low Pt loading

• Published in: International journal of hydrogen energy Vol. 42; no. 9; pp. 6250 - 6261
• Main Authors: Öztürk, Ayşenur, Bayrakçeken Yurtcan, Ayşe
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 02.03.2017
• Subjects: Hydrophobicity; Microporous layer; PDMS; PEM fuel cell; Water management; Water management; Microporous layer; Hydrophobicity; PDMS; PEM fuel cell
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2016.11.041

Water management is the most critical issue for the reliable PEM fuel cell operation. Microporous layer (MPL) is an important component of gas diffusion media and its hydrophobicity affects the water removal capability of the cell. Hydrophobic property changes with different parameters and in this study, the effect of calcination temperature on the hydrophobicity of the MPLs was investigated. MPLs were prepared with two different molecular weights of polydimethylsiloxane (PDMS) polymer and they were calcined at different temperatures. The results show that calcination temperature has considerable effect on the hydrophobic characteristic of the MPL. The fuel cell MPL prepared with lower molecular weight of PDMS and calcined at 300 °C gives the best performance even though its hydrophilic character. [Display omitted] •PDMS polymer was used as novel hydrophobic material in the MPL structure.•The effect of different molecular weight of PDMS on the MPL hydrophobicity was investigated.•Calcination temperature is effective parameter to modify wetting characteristic of MPL surface.•It was obtained agreeable performance results despite low Pt loading.