Co/Ti co-substituted layered LiNiO2 prepared using a concentration gradient method as an effective cathode material for Li-ion batteries

• Published in: Journal of power sources Vol. 372; pp. 107 - 115
• Main Authors: Ko, Hyoung Shin, Kim, Jea Han, Wang, Juan, Lee, Jong Dae
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 31.12.2017
• Subjects: Concentration gradient; Crystalline stability; Elemental substitution; Li-ion batteries; Oxygen loss; Titanium; Titanium; Elemental substitution; Oxygen loss; Li-ion batteries; Crystalline stability; Concentration gradient
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2017.10.021

The design of Li-ion batteries with high energy storage capacities and efficiencies is a subject of increased research interest, being of key importance for their large-scale applications and further commercialization. However, conventional Li-ion batteries are expensive and have stability-related concerns, which limit their practical applications. In our search for cheaper and safer Li-ion batteries, we use a concentration gradient method to prepare LiNi0.9Co0.1–xTixO2 (0.02 ≤ x ≤ 0.05) cathode materials surface-enriched with Co and Ti that exhibit decreased oxygen loss and improved structural stability. The corresponding crystal structures and morphologies are analyzed by X-ray diffraction and field emission scanning electron microscopy, with the Ni, Co, and Ti concentration distributions determined by energy-dispersive X-ray spectroscopy. The material with the best performance (x = 0.04) exhibits a discharge capacity of 214 mAh g−1 in a charge/discharge voltage range of 3.0–4.3 V (vs. Li/Li+), and possesses an excellent 50-cycle capacity retention of 98.7%. Thermogravimetric analysis shows that partial substitution of Ni with the strongly oxophilic Ti solves the problem of oxygen loss observed in Ni-rich cathode materials such as LiNiO2. •Concentration-gradient LiNi0.9Co0.1–xTixO2 cathode materials were prepared.•These materials exhibit decreased oxygen loss and improved structural stability.•Best performance observed for x = 0.04.•LiNi0.9Co0.06Ti0.04O2 exhibits a discharge capacity of 214 mAh g−1.•LiNi0.9Co0.06Ti0.04O2 exhibits an excellent 50-cycle capacity retention of 98.7%.