A new reusable adsorbent of polyvinyl alcohol/magnesium peroxide (PVA/MgO2) for highly selective adsorption and dye removal

• Published in: Materials chemistry and physics Vol. 270; p. 124820
• Main Authors: Al Naim, Abdullah F., El-Shamy, Ahmed G.
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 15.09.2021; Elsevier BV
• Subjects: Adsorbents; Adsorption; Adsorption capacity; Catalytic activity; Dyes; Magnesium; MgO2 particles; Nanocomposites; Optical properties; Polyvinyl alcohol; PVA; Selective adsorption; Surface charge; Surface chemistry; Adsorption capacity; PVA; MgO2 particles; Optical properties; Selective adsorption
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2021.124820

New adsorbent polyvinyl alcohol/magnesium peroxide (PVA/MgO2) nano-composite films have been designed for high selective adsorption and dye removal applications. Creation of MgO2 within 40 ± 3 nm has been confirmed by TEM. PVA/MgO2 films have a large surface area of 59.130 m2 g−1, high pore volume 0.191 cm3 g−1 and a high negative surface charge _ 36.4 mV at pH environment ~12, which plays an important role in increasing the uptake capacity, removal efficiency and the selective adsorption performance. PVA/MgO2 nano-composite shows a high selective adsorption for MB dyes from a mixture solution containing both MB and MO dyes. Experiments showed that 30 mg of PVA/MgO2 has the ability to remove 50 mL of 25 mg/L of MB dye with an efficiency (99.9 ± 0.1%) in a fast time ~15 min under the experimental conditions. The Langmuir model is the isotherm model, the pseudo second order is the adsorption kinetics as well as the exothermic is thermodynamic process of the adsorption process. In addition, PVA/MgO2 nano-composite shows a high catalytic activity, in the recycling test, for ten cycles of MB adsorption. [Display omitted] •New PVA/MgO2 nanocomposites were prepared by casing method for selecting and removing MB dyes for the first time.•PVA/MgO2 has a high surface area of 59.130 m2 g−1 and a high negative surface charge _ 36.4 mV.•PVA/MgO2 shows a high catalytic selectivity for MB dyes from mixture solution containing both MB and MO dyes.•30 mg of PVA/MgO2 has the ability to remove 50 mL of 25 mg/L of MB dye with efficiency (99.9 ± 0.1%) in a fast time 15 min.•PVA/MgO2 shows a high catalytic activity, in the recycling test, for ten cycles of MB degradation.