Catalytic Conversions in Water. Part 21: Mechanistic Investigations on the Palladium-Catalysed Aerobic Oxidation of Alcohols in Water

Water‐soluble complexes of palladium(II) with phenanthroline‐derivatives are stable, recyclable catalysts for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic liquid‐liquid system. The active catalyst is a dihydroxy‐bridged palladi...

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Published inAdvanced synthesis & catalysis Vol. 344; no. 3-4; pp. 355 - 369
Main Authors ten Brink, Gerd-Jan, Arends, Isabel W. C. E., Sheldon, Roger A.
Format Journal Article
LanguageEnglish
Published Weinheim WILEY-VCH Verlag GmbH 01.06.2002
WILEY‐VCH Verlag GmbH
Subjects
alcohols
kinetics
oxidation
palladium
water as solvent
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Summary:Water‐soluble complexes of palladium(II) with phenanthroline‐derivatives are stable, recyclable catalysts for the selective aerobic oxidation of a wide range of alcohols to aldehydes, ketones, and carboxylic acids in a biphasic liquid‐liquid system. The active catalyst is a dihydroxy‐bridged palladium dimer. Kinetics of the reaction, ligand and anion effects are discussed.
Bibliography:istex:51EE325D609D75C6D6DB0D9DC4B25650570D389E
ark:/67375/WNG-6M3ZMXP8-F
ArticleID:ADSC355
ISSN:1615-4150
1615-4169
DOI:10.1002/1615-4169(200206)344:3/4<355::AID-ADSC355>3.0.CO;2-S