Photo-induced Living Cationic Copolymerization of Isobutyl Vinyl Ether and Vinyl Ether with Carbazolyl Groups

In this work, a fluorescent monomer 2-（9-carbazolyl） ethyl vinyl ether（CEVE） was synthesized in our lab, and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether（IBVE） was investigated in detail using diphenyliodonium chloride（DPICl）/2,2-dimethoxy-2-phenylacetophenon...

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Bibliographic Details
Published inChinese journal of polymer science Vol. 32; no. 11; pp. 1564 - 1574
Main Authors Li, Ming, Zhang, Li-fen, Tao, Mei-xia, Cheng, Zhen-ping, Zhu, Xiu-lin
Format Journal Article
LanguageEnglish
Published Heidelberg Chinese Chemical Society and Institute of Chemistry, CAS 01.11.2014
Subjects
Cationic
Characterization and Evaluation of Materials
Chemistry
Chemistry and Materials Science
Chlorides
Condensed Matter Physics
Copolymerization
Copolymers
Fluorescence
Industrial Chemistry/Chemical Engineering
Monomers
Polymer Sciences
Vinyl ethers
Zinc
乙基乙烯基醚
光诱导
咔唑
异丁基乙烯基醚
活性
玻璃化转变温度
荧光单体
阳离子共聚
Copolymerization
Cationic polymerization
Living cationic polymerization
Kinetics (polym.)
Photopolymerization
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Summary:In this work, a fluorescent monomer 2-（9-carbazolyl） ethyl vinyl ether（CEVE） was synthesized in our lab, and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether（IBVE） was investigated in detail using diphenyliodonium chloride（DPICl）/2,2-dimethoxy-2-phenylacetophenone（DMPA） and zinc bromide（Zn Br2） initiating system in dichloromethane solution at 5 °C, -5 °C, and -15 °C, respectively. The living nature of this copolymerization system was confirmed by adding fresh comonomer method after the copolymerization almost finished. In addition, the obtained fluorescent copolymer poly（IBVE-co-CEVE） has a low glass transition temperature（Tg）, below -10 °C.
Bibliography:In this work, a fluorescent monomer 2-（9-carbazolyl） ethyl vinyl ether（CEVE） was synthesized in our lab, and its photo-induced living cationic copolymerization behavior with isobutyl vinyl ether（IBVE） was investigated in detail using diphenyliodonium chloride（DPICl）/2,2-dimethoxy-2-phenylacetophenone（DMPA） and zinc bromide（Zn Br2） initiating system in dichloromethane solution at 5 °C, -5 °C, and -15 °C, respectively. The living nature of this copolymerization system was confirmed by adding fresh comonomer method after the copolymerization almost finished. In addition, the obtained fluorescent copolymer poly（IBVE-co-CEVE） has a low glass transition temperature（Tg）, below -10 °C.
Photopolymerization;Kinetics（polym.）;Copolymerization;Cationic polymerization;Living cationic polymerization.
11-2015/O6
ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:0256-7679
1439-6203
DOI:10.1007/s10118-014-1540-8