Thermal and structural characterization of copper(II) complexes with phenyl-2-pyridylketoxime (HPPK)
Copper(II) complexes of different nuclearity with phenyl-2-pyridylketoxime (HPPK), such as mononuclear [Cu(HPPK)(PPK)X], whereby X = NCS − (1) or NO 3 − (2) , dinuclear [Cu(HPPK)Cl 2 ] 2 (3) and trinuclear [Cu 3 (PPK) 3 (μ 3 –OH)(Cl) 2 ]· n H 2 O (4) were synthesized, and their thermal properties w...
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Published in | Journal of thermal analysis and calorimetry Vol. 128; no. 3; pp. 1591 - 1599 |
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Main Authors | , , , |
Format | Journal Article |
Language | English |
Published |
Dordrecht
Springer Netherlands
01.06.2017
Springer Nature B.V |
Subjects | |
Online Access | Get full text |
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Summary: | Copper(II) complexes of different nuclearity with phenyl-2-pyridylketoxime (HPPK), such as mononuclear [Cu(HPPK)(PPK)X], whereby
X
= NCS
−
(1)
or NO
3
−
(2)
, dinuclear [Cu(HPPK)Cl
2
]
2
(3)
and trinuclear [Cu
3
(PPK)
3
(μ
3
–OH)(Cl)
2
]·
n
H
2
O
(4)
were synthesized, and their thermal properties were investigated. The studies involved gas-phase monitoring of decomposition products by infrared spectroscopy. Thermal decomposition performed in air revealed the multi-stage character of the process, the course of which depends on the compound composition. In all cases, CuO was found as the final product of the process. Furthermore, the crystal structure of
1
was revealed. It shows a square-pyramidal geometry around Cu(II), with the NCS
−
ion situated in the apical position and two HPPK ligands present in the base, one of which is deprotonated. |
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ISSN: | 1388-6150 1588-2926 |
DOI: | 10.1007/s10973-016-5956-y |