High proton conduction in an excellent water-stable gadolinium metal–organic framework
A new metal–organic framework with excellent water stability, {H[(N(CH 3 ) 4 ) 2 ][Gd 3 (NIPA) 6 ]}·3H 2 O (1, H 2 NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10 −2 S cm −1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOF...
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| Published in | Chemical communications (Cambridge, England) Vol. 55; no. 9; pp. 1241 - 1244 |
|---|---|
| Main Authors | , , , , , |
| Format | Journal Article |
| Language | English |
| Published |
England
Royal Society of Chemistry
24.01.2019
|
| Subjects | |
| Online Access | Get full text |
| ISSN | 1359-7345 1364-548X 1364-548X |
| DOI | 10.1039/C8CC08700H |
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| Abstract | A new metal–organic framework with excellent water stability, {H[(N(CH
3
)
4
)
2
][Gd
3
(NIPA)
6
]}·3H
2
O (1, H
2
NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10
−2
S cm
−1
(at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. |
|---|---|
| AbstractList | A new metal–organic framework with excellent water stability, {H[(N(CH₃)₄)₂][Gd₃(NIPA)₆]}·3H₂O (1, H₂NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10⁻² S cm⁻¹ (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10-2 S cm-1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10-2 S cm-1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs.A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10-2 S cm-1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. A new metal–organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10−2 S cm−1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. A new metal–organic framework with excellent water stability, {H[(N(CH 3 ) 4 ) 2 ][Gd 3 (NIPA) 6 ]}·3H 2 O (1, H 2 NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10 −2 S cm −1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs. |
| Author | Wang, Ming-Sheng Guo, Guo-Cong Zhang, Ning-Ning Xing, Xiu-Shuang Yu, Xiao-Qing Fu, Zhi-Hua |
| Author_xml | – sequence: 1 givenname: Xiu-Shuang surname: Xing fullname: Xing, Xiu-Shuang organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China – sequence: 2 givenname: Zhi-Hua surname: Fu fullname: Fu, Zhi-Hua organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China – sequence: 3 givenname: Ning-Ning surname: Zhang fullname: Zhang, Ning-Ning organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China – sequence: 4 givenname: Xiao-Qing surname: Yu fullname: Yu, Xiao-Qing organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China – sequence: 5 givenname: Ming-Sheng orcidid: 0000-0002-2400-719X surname: Wang fullname: Wang, Ming-Sheng organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China – sequence: 6 givenname: Guo-Cong orcidid: 0000-0002-7450-9702 surname: Guo fullname: Guo, Guo-Cong organization: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, P. R. China |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/30632553$$D View this record in MEDLINE/PubMed |
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| Snippet | A new metal–organic framework with excellent water stability, {H[(N(CH
3
)
4
)
2
][Gd
3
(NIPA)
6
]}·3H
2
O (1, H
2
NIPA = 5-nitroisophthalic acid), displays a... A new metal-organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton... A new metal–organic framework with excellent water stability, {H[(N(CH3)4)2][Gd3(NIPA)6]}·3H2O (1, H2NIPA = 5-nitroisophthalic acid), displays a proton... A new metal–organic framework with excellent water stability, {H[(N(CH₃)₄)₂][Gd₃(NIPA)₆]}·3H₂O (1, H₂NIPA = 5-nitroisophthalic acid), displays a proton... |
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| SubjectTerms | chemical reactions coordination polymers Crystallography Gadolinium Metal-organic frameworks Proton conduction quaternary ammonium compounds Relative humidity Tables Water stability |
| Title | High proton conduction in an excellent water-stable gadolinium metal–organic framework |
| URI | https://www.ncbi.nlm.nih.gov/pubmed/30632553 https://www.proquest.com/docview/2170616902 https://www.proquest.com/docview/2179376813 https://www.proquest.com/docview/2220869322 |
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