High proton conduction in an excellent water-stable gadolinium metal–organic framework

A new metal–organic framework with excellent water stability, {H[(N(CH 3 ) 4 ) 2 ][Gd 3 (NIPA) 6 ]}·3H 2 O (1, H 2 NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10 −2 S cm −1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOF...

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Published inChemical communications (Cambridge, England) Vol. 55; no. 9; pp. 1241 - 1244
Main Authors Xing, Xiu-Shuang, Fu, Zhi-Hua, Zhang, Ning-Ning, Yu, Xiao-Qing, Wang, Ming-Sheng, Guo, Guo-Cong
Format Journal Article
LanguageEnglish
Published England Royal Society of Chemistry 24.01.2019
Subjects
chemical reactions
coordination polymers
Crystallography
Gadolinium
Metal-organic frameworks
Proton conduction
quaternary ammonium compounds
Relative humidity
Tables
Water stability
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Summary:A new metal–organic framework with excellent water stability, {H[(N(CH 3 ) 4 ) 2 ][Gd 3 (NIPA) 6 ]}·3H 2 O (1, H 2 NIPA = 5-nitroisophthalic acid), displays a proton conductivity of 7.17 × 10 −2 S cm −1 (at 75 °C and 98% relative humidity), which is among the highest values for proton-conducting MOFs.
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ISSN:1359-7345
1364-548X
1364-548X
DOI:10.1039/C8CC08700H