Supported gold nanoparticle catalyst for the selective oxidation of silanes to silanols in water

Hydroxyapatite-supported gold nanoparticles (AuHAP) can act as highly efficient and reusable catalysts for the oxidation of diverse silanes into silanols in water; this is the first catalytic methodology for the selective synthesis of aliphatic silanols using water under organic-solvent-free conditi...

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Published inChemical communications (Cambridge, England) no. 35; pp. 5302 - 5304
Main Authors Mitsudome, Takato, Noujima, Akifumi, Mizugaki, Tomoo, Jitsukawa, Koichiro, Kaneda, Kiyotomi
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2009
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
INSERTION
CARBON
ALKENYLSILANOLS
ORGANOSILANES
STEREOCHEMISTRY
SILICON
EFFICIENT
HYDROLYTIC OXIDATION
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Summary:Hydroxyapatite-supported gold nanoparticles (AuHAP) can act as highly efficient and reusable catalysts for the oxidation of diverse silanes into silanols in water; this is the first catalytic methodology for the selective synthesis of aliphatic silanols using water under organic-solvent-free conditions.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
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ISSN:1359-7345
1364-548X
DOI:10.1039/b910208f