Spirocyclic boronium ions: precursors to persistent neutral radicals

Spirocyclic boronium ions based on the 9-bora-9,10-dihydroanthracene scaffold and substituted 2,2'-bipyridyl ligands have been prepared; these cations are shown to be convenient starting materials for the preparation of neutral radicals with significant spin density on boron.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 34; pp. 5147 - 5149
Main Authors Wood, Thomas K., Piers, Warren E., Keay, Brian A., Parvez, Masood
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 01.01.2009
Subjects
Boron Compounds - chemical synthesis
Boron Compounds - chemistry
Chemistry
Chemistry, Multidisciplinary
Computer Simulation
Crystallography, X-Ray
Free Radicals - chemistry
Ions - chemical synthesis
Ions - chemistry
Models, Chemical
Models, Molecular
Molecular Structure
Physical Sciences
Science & Technology
Spiro Compounds - chemical synthesis
Spiro Compounds - chemistry
CONDUCTORS
BORINIUM
CHEMISTRY
N-HETEROCYCLIC CARBENES
BORENIUM
SPECTRA
SALTS
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Summary:Spirocyclic boronium ions based on the 9-bora-9,10-dihydroanthracene scaffold and substituted 2,2'-bipyridyl ligands have been prepared; these cations are shown to be convenient starting materials for the preparation of neutral radicals with significant spin density on boron.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1359-7345
1364-548X
DOI:10.1039/b911982e