An azido-metal-isonicotinate complex showing long-range ordered ferromagnetic interaction: synthesis, structure and magnetic properties

A new 3D Cu(II) complex [Cu1.5(N3)2(isonicotinate)]n [1], which features two types of bridging modes for azide (mu(1,1) and the rare asymmetric mu(1,1,3)) where the three bonds of the mu(1,1,3)-N3(-) group to Cu exhibit three different distances, has been synthesized and characterized, and magnetic...

Full description

Saved in:
Bibliographic Details
Published inChemical communications (Cambridge, England) no. 21; p. 2227
Main Authors Zeng, Yong-Fei, Liu, Fu-Chen, Zhao, Jiong-Peng, Cai, Shuang, Bu, Xian-He, Ribas, Joan
Format Journal Article
LanguageEnglish
Published England 01.01.2006
Online AccessGet more information

Cover

More Information
Summary:A new 3D Cu(II) complex [Cu1.5(N3)2(isonicotinate)]n [1], which features two types of bridging modes for azide (mu(1,1) and the rare asymmetric mu(1,1,3)) where the three bonds of the mu(1,1,3)-N3(-) group to Cu exhibit three different distances, has been synthesized and characterized, and magnetic measurements indicate that [1] experiences long-range ferromagnetic ordering at approximately 6 K.
ISSN:1359-7345
DOI:10.1039/b601311b