Template directed photodimerization of trans-1,2-bis(n-pyridyl)-ethylenes and stilbazoles in water

Template induced photodimerization of trans-1,2-bis(n-pyridyl) ethylene dihydrochlorides and trans-n-stilbazole hydrochlorides within cucurbit[8]uril in aqueous media leads to high yields of the syn dimer.

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Bibliographic Details
Published inChemical communications (Cambridge, England) no. 36; pp. 4542 - 4544
Main Authors Pattabiraman, M, Natarajan, A, Kaliappan, R, Mague, JT, Ramamurthy
Format Journal Article
LanguageEnglish
Published CAMBRIDGE Royal Soc Chemistry 28.09.2005
Subjects
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
SUPRAMOLECULAR CONTROL
SINGLE-CRYSTAL TRANSFORMATION
PHOTOCHEMICAL REACTIVITY
PHOTO-DIMERIZATION
GAMMA-CYCLODEXTRIN
PHOTOCYCLIZATION
CUCURBITURIL
DERIVATIVES
SOLID-STATE
STEREOSELECTIVE PHOTODIMERIZATION
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Summary:Template induced photodimerization of trans-1,2-bis(n-pyridyl) ethylene dihydrochlorides and trans-n-stilbazole hydrochlorides within cucurbit[8]uril in aqueous media leads to high yields of the syn dimer.
ISSN:1359-7345
1364-548X
DOI:10.1039/b508458j