Metal-hydride hydrogen atom transfer (MHAT) reactions in natural product synthesis

The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the field of natural product synthesis. MHAT, as a powerful method, has been employed by chemists to construct C–C, C–H, and C–heteroatom bonds. In this review, we summarize the recent total synthesis of natural prod...

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Published inOrganic chemistry frontiers an international journal of organic chemistry Vol. 8; no. 24; pp. 7050 - 7076
Main Authors Wu, Jinghua, Ma, Zhiqiang
Format Journal Article
LanguageEnglish
Published London Royal Society of Chemistry 07.12.2021
Subjects
Alkenes
Catalysts
Chemical synthesis
Chemists
Cobalt
Manganese
Metal hydrides
Natural products
Organic chemistry
Transition metals
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Summary:The metal-hydride hydrogen atom transfer (MHAT) reaction plays an important role in the field of natural product synthesis. MHAT, as a powerful method, has been employed by chemists to construct C–C, C–H, and C–heteroatom bonds. In this review, we summarize the recent total synthesis of natural products using MHAT to functionalize olefins with first-row transition metal catalysts such as cobalt, manganese and iron.
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ISSN:2052-4110
2052-4110
DOI:10.1039/d1qo01139a