A novel sodium-ion supercabattery based on vacancy defective Ni-Co-Mn ternary perovskite fluoride electrode materials

• Published in: Journal of materials chemistry. A, Materials for energy and sustainability Vol. 9; no. 25; pp. 14276 - 14284
• Main Authors: Yan, Tong, Ding, Rui, Huang, Yongfa, Ying, Danfeng, Tan, Caini, Huang, Yuxi, Yang, Feng, Sun, Xiujuan, Gao, Ping, Liu, Enhui
• Format: Journal Article
• Language: English
• Published: Cambridge Royal Society of Chemistry 07.07.2021
• Subjects: Activated carbon; Anode effect; Batteries; Capacitors; Cathodes; Conversion; Electrochemistry; Electrode materials; Energy storage; Fluorides; Graphene; Intercalation; Manganese; Nickel; Perovskites; Rechargeable batteries; Sodium; Sodium-ion batteries; Specific capacity; Synergistic effect; Vacancies
• ISSN: 2050-7488; 2050-7496
• DOI: 10.1039/d1ta02894d

In this work, we have proposed a new concept of sodium-ion supercabatteries ( i.e. , sodium-ion capacitors/batteries, SICBs) based on a novel vacancy defective Ni-Co-Mn ternary perovskite fluoride K 0.71 Ni 0.12 Co 0.41 Mn 0.47 F 2.77 /reduced graphene oxide ( i.e. , KMF(244)/rGO) anode and a capacitor/battery (activated carbon/Na 3 V 2 (PO 4 ) 2 O 2 F, i.e. , AC/NVPOF) hybrid cathode, which reduce the gap between sodium-ion capacitors (SICs) and sodium-ion batteries (SIBs). The KMF(244)/rGO anode, with the synergistic effect of Ni, Co, and Mn redox species and K/F vacancy defects, presents remarkable specific capacity, rate and cycle performance, showing pseudocapacitive-dominated conversion/intercalation dual mechanisms. Interestingly, the KMF(244)/rGO//AC/NVPOF SICBs exhibit superior performance to KMF(244)/rGO//AC SICs and KMF(244)/rGO//NVPOF SIBs, which largely benefits from the synergistic energy storage superiority of SICs and SIBs showing pseudocapacitive, capacitive, and faradaic behavior in electrochemical processes. To sum up, our study presents a novel concept of sodium-ion supercabatteries realized by using the vacancy defective Ni-Co-Mn ternary perovskite fluoride anode with pseudocapacitive-dominated conversion/intercalation dual mechanisms and an AC/NVPOF capacitor/battery hybrid cathode, providing new insight into developing advanced energy storage devices and in-depth understanding of the charge storage mechanisms. Proposal of a new concept of sodium-ion supercabatteries based on a novel vacancy defective Ni-Co-Mn ternary perovskite fluoride K 0.71 Ni 0.12 Co 0.41 Mn 0.47 F 2.77 /rGO anode and an activated carbon/Na 3 V 2 (PO 4 ) 2 O 2 F hybrid cathode.